java.net.MalformedURLException: no protocol: /Users/Arun/Documents/employeeInfo.xml

Getting this exception while read xml file using SmbJcifs :-

java.net.MalformedURLException: no protocol: /Users/Arun/Documents/employeeInfo.xml
 at java.net.URL.(URL.java:567)
 at jcifs.smb.SmbFile.(SmbFile.java:437)
 at test.ReadXMLFile.readxmldata(ReadXMLFile.java:78)
 at test.ReadXMLFile.main(ReadXMLFile.java:29)
Exception in thread "main" java.lang.IllegalArgumentException: File cannot be null
 at javax.xml.parsers.DocumentBuilder.parse(DocumentBuilder.java:201)
 at test.ReadXMLFile.main(ReadXMLFile.java:33)

Reason for This url or path string looks like it's invalid. in smb it's not supposed to be '/Users/Arun/Documents/employeeInfo.xml' directory.
Url pattern of smb (smb://IPADDRESS/Volume/Folder/) where file located. when i change to this (smb:// URL syntax) every thing goes very well.

:) :)